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AbstractThe reactivity of calcite, one of the most abundant minerals in the earth’s crust, is determined by the molecular details of its interface with the contacting solution. Recently, it has been found that trace concentrations of NaNO3 severely affect calcite’s (104) surface and its reactivity. Here we combine molecular dynamics (MD) simulations, X ray reflectivity (XR) and in situ atomic force microscopy (AFM) to probe the calcite (104) water interface in the presence of NaNO3.
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